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This paper analyzes fuel economy benefits of direct hydrogen and gasoline reformer fuel cell vehicles, with special focus on cold-start impacts on these fuel cell based vehicles. Comparing several existing influential studies reveals that the most probable estimates from these studies differ greatly on the implied benefits of both types of fuel cell vehicles at the tank-to-wheel level (vehicle-powertrain efficiency and/or specific power), leading to great uncertainties in estimating well-to-wheel fuel energy and/or greenhouse gas (GHG) emission reduction potentials. This paper first addresses methodological issues to influence the outcome of these analyses. With one exception, we find that these studies consistently ignore cold-start and warm-up issues, which play important roles in determining both energy penalties and start-up time of fuel cell vehicles. To better understand cold-start and warm-up behavior, this paper examines approaches and results based on two available U.S.

The importance of radiative heat transfer on the combustion and soot formation characteristics under nominal ECN Spray A conditions has been studied numerically. The liquid n-dodecane fuel is injected with 1500 bar fuel pressure into the constant volume chamber at different ambient conditions. Radiation from both gas-phase as well as soot particles has been included and assumed as gray. Three different solvers for the radiative transfer equation have been employed: the discrete ordinate method, the spherical-harmonics method and the optically thin assumption. The radiation models have been coupled with the transported probability density function method for turbulent reactive flows and soot, where unresolved turbulent fluctuations in temperature and composition are included and therefore capturing turbulence-chemistry-soot-radiation interactions. Results show that the gas-phase (mostly CO2 ad H2O species) has a higher contribution to the net radiation heat transfer compared to soot.

Cold starting problems of diesel engines are caused mainly by the failure of the auto-ignition process or the subsequent combustion of the rest of the charge. The problems include long cranking periods and combustion instability leading to an increase in fuel consumption in addition to the emission of undesirable unburned hydrocarbons which appear in the exhaust as white smoke. The major cause of these problems is the low temperature and pressure of the charge near the end of the compression stroke and/or the poor ignition quality of the fuel. This paper presents the results of an experimental investigation of cold starting of a high speed diesel engine with ULSD (Ultra Low Sulphur Diesel) and JP8 (Jet Propulsion) fuels at ambient temperature (25°C). A detailed analysis is made of the autoignition and combustion of the two fuels in the first few cycles in the cold start transient. In addition, a comparison is made between these processes for the two fuels during idle operation.

An automotive powertrain system consists of several interactive and linked nonlinear systems. This research focuses on the coordination of Gasoline Direct Injection (GDI) engine, transmission and emission aftertreatment systems. The goal is to design an optimal control strategy for driving performance, emissions (HC, CO, NOX), fuel economy and smoothness when switching engine mode and when shifting gears, under both discrete and continuous limitations. A multivariable control strategy is used to compromise among all powertrain subsystems to achieve optimal overall performance. A nonlinear discrete dynamic programming approach is proposed for hybrid system optimization. The complex multivariable automotive control problem is then simplified into an optimization problem. The feasibility of automotive hybrid control via the discrete dynamic programming approach is demonstrated by results from many numerical simulations under different operating conditions.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Using natural gas in an internal combustion engine (ICE) is emerging as a promising way to improve thermal efficiency and reduce exhaust emissions. In the development of such engine platforms, computational fluid dynamics (CFD) plays a fundamental role in the optimization of geometries and operating parameters. One of the most relevant issues in the simulation of direct injection (DI) gaseous processes is the accurate prediction of the gas jet evolution. The simulation of the injection process for a gaseous fuel does not require complex modeling, nevertheless properly describing high-pressure gas jets remains a challenging task. At the exit of the nozzle, the injected gas is under-expanded, the flow becomes supersonic and shocks occur due to compressibility effects. These phenomena lead to challenging computational requirements resulting from high grid resolution and low computational time-steps.

Emissions from CI engines fueled with dimethyl ether (DME) were discussed in this paper. Thanks to its high content of fuel oxygen, DME combustion is virtually soot free. This characteristic of DME combustion indicates that the particulate filter will not be needed in the aftertreatment system for engines fueled with DME. NOx emissions from a CI engine fueled with DME can meet the US 2007 regulation with a high EGR rate. Because 49% more fuel mass must be delivered in each DME injection than the corresponding diesel-fuel injection, and the DME injection pressure is lower than 500 bar under the current fuel-system technology, the DME injection duration is generally longer than that of diesel-fuel injection. This is unfavorable to further NOx reduction. A multiple-injection strategy with timing for the primary injection determined by the cylinder temperature was proposed.

A key strategy to improving the real-world fuel consumption and emissions of medium and heavy duty vehicles is the hybridization of these applications. Unlike the passenger vehicle market, medium and heavy duty applications are typically comprised of a range of components from a variety of manufacturers. The vocational market diversity and size places considerable demand on fuel efficiency and emission compliance. Medium and heavy duty applications have the ability to be successfully hybridized in ways that are not currently, or would not be practical within a passenger vehicle. This would also drive greater truck and bus vertical integration of the hybrid components. However, medium and heavy duty manufacturers have been prevented from certifying a full vehicle level platform due to the current engine only certification requirements.

Gasoline is a complex fuel. Many of the constituents of gasoline that are beneficial for the internal combustion engine (ICE) are expected to be challenging for on-board reformers in fuel-cell vehicles. To address these issues, the autothermal reforming of gasoline and individual components of gasoline has been investigated. The results indicate that aromatic components require higher temperatures and longer contact times to reform than paraffinic components. Napthenic components require higher temperatures to reform, but can be reformed at higher space velocities than paraffinic components. The effects of sulfur are dependent on the catalyst. These results suggest that further evolution of gasoline could reduce the demands on the reformer and provide a better fuel for a fuel-cell vehicle.

The direct injection gasoline spray-wall interaction was characterized inside a heated pressurized chamber using various visualization techniques, including high-speed laser-sheet macroscopic and microscopic movies up to 25,000 frames per second, shadowgraph, and doublespark particle image velocimetry. Two hollow cone high-pressure swirl injectors having different cone angles were used to inject gasoline onto a heated plate at two different impingement angles. Based on the visualization results, the overall transient spray impingement structure, fuel film formation, and preliminary droplet size and velocity were analyzed. The results show that upward spray vortex inside the spray is more obvious at elevated temperature condition, particularly for the wide-cone-angle injector, due to the vaporization of small droplets and decreased air density. Film build-up on the surface is clearly observed at both ambient and elevated temperature, especially for narrow cone spray.

At the current stage of engine technology, diesel engines typically require diesel particulate filter (DPF) systems to meet recent particulate emissions standards. To assure the performance and reliability of DPF systems, profound understanding of filtration and regeneration mechanisms is required. Among extensive efforts for developing advanced DPF systems, the development of effective thermal management strategies, which control the thermal runaway taking place in oxidation of an excess amount of soot deposit in DPF, is quite challenging. This difficulty stems mainly from lack of sufficient knowledge and understanding about DPF regeneration mechanisms, which need detailed information about oxidation of diesel particulate matter (PM). Therefore, this work carried out a series of oxidation experiments of diesel particulates collected from a DPF on a diesel engine, and evaluated the oxidation rates of the samples using a thermo-gravimetric analyzer (TGA).

Detailed characteristics of morphology, nanostructures, and sizes were analyzed for particulate matter (PM) emissions from low-temperature combustion (LTC) modes of a single-cylinder, light-duty diesel engine. The LTC engines have been widely studied in an effort to achieve high combustion efficiency and low exhaust emissions. Recent reports indicate that the number of nucleation mode particles increased in a broad engine operating range, which implies a negative impact on future PM emissions regulations in terms of the nanoparticle number. However, the size measurement of solid carbon particles by commercial instruments is indeed controversial due to the contribution of volatile organics to small nanoparticles. In this work, an LTC engine was operated with various biofuel blends, such as blends (B20) of soy bean oil (soy methyl ester, SME20) and palm oil (palm methyl ester, PME20), as well as an ultra-low-sulfur diesel fuel.

Early in 2007 President Bush announced in his State of the Union Address a plan to off-set 20% of gasoline with alternative fuels in the next ten years. Ethanol, due to its excellent fuel properties for example, high octane number, renewable character, etc., appears to be a favorable alternative fuel from an engine perspective. Replacing gasoline with ethanol without any additional measures results in unacceptable disadvantages mainly in terms of vehicle range. This paper summarizes combustion studies performed with gasoline as well as blends of gasoline and ethanol. These tests were performed on a modern, 4-cylinder spark ignition engine with direct fuel injection and exhaust gas recirculation. To evaluate the influence of blending on the combustion behavior the engine was operated on the base gasoline calibration. Cylinder pressure data taken during the testing allowed for detailed analysis of rates of heat release and combustion stability.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

"The Single Fuel Forward Policy" legislation enacted in the United States mandates that deployed U.S. military ground vehicles must be operable with aviation fuel (JP-8). This substitution of JP-8 for diesel raises concerns about the compatibility of this fuel with existing reciprocating piston engine systems. This study investigates the combustion, emissions, and performance characteristics of blends of JP-8 and Ultra Low Sulfur Diesel (ULSD) fuels with similar cetane numbers (CN), 48 (JP-8) and 47(ULSD), respectively, in a direct injection (DI) compression ignition engine over the load range of 3-8 bar imep at 1400 rpm. The results showed that JP-8 blends and ULSD had ignition delays ranging from approximately 1.0-1.4 ms and an average combustion duration time in the range of 47-65 CAD. Cylinder maximum heat flux values were found to be between 2.0 and 4.4 MW/m₂, with radiation flux increasing much faster than convection flux while increasing the imep.

Because of their high efficiency and low emissions, fuel-cell vehicles are undergoing extensive research and development. When considering the introduction of advanced vehicles, a complete well-to-wheel evaluation must be performed to determine the potential impact of a technology on carbon dioxide and Green House Gases (GHGs) emissions. Several modeling tools developed by Argonne National Laboratory (ANL) were used to evaluate the impact of advanced powertrain configurations. The Powertrain System Analysis Toolkit (PSAT) transient vehicle simulation software was used with a variety of fuel cell system models derived from the General Computational Toolkit (GCtool) for pump-to-wheel (PTW) analysis, and GREET (Green house gases, Regulated Emissions and Energy use in Transportation) was used for well-to-pump (WTP) analysis. This paper compares advanced propulsion technologies on a well-to-wheel energy basis by using current technology for conventional, hybrid and fuel cell technologies.

Gas-to-Liquids (GTL) is a liquid diesel fuel produced from natural gas, which may have certain attributes different from conventional ultra low sulfur diesel (ULSD). In this investigation, GTL, ULSD, and their blends of 20% and 50% GTL in ULSD were tested in an older Mercedes C Class (MY1999, Euro 2) and a newer Opel Astra (MY2006, Euro 4) diesel vehicle to evaluate the performance in terms of fuel consumption and emissions. Each vehicle was pre-conditioned on-road with one tank full of test fuel before actual testing in a chassis dynamometer facility. Both vehicles were calibrated for European emission standards and operation, and they were not re-calibrated for the fuel tests at Argonne National Laboratory (ANL). In the two-vehicle EPA FTP-75, US06, and Highway drive-cycle tests, the emissions of carbon dioxide on a per-mile basis (g/mi) from all GTL-containing fuels were significantly lower than those from the ULSD.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.